For the first time the method of the maximum pressure in a vial of gas received values of density of the melted mixes LiCl-ZrF4 and LiCl-KF-ZrF4. In three-component salt systems research is conducted at the molar and share ratio of halogenides of alkaline metals equal 1 : 3, 1 : 1, 3 : 1. For all structures of fusions temperature dependences of density were found. Molar volumes and their relative deviations from ideality of salt mixes of LiCl-ZrF4 and LiCl-KF-ZrF4 systems are calculated. Conclusions concerning structure of the studied fusions from a position of modern representations of a structure of ionic liquids are drawn.
|Translated title of the contribution||Volume properties of LiCl-KF-ZrF4 system melts|
|Number of pages||6|
|Publication status||Published - 2015|
- 31.00.00 CHEMISTRY
Level of Research Output
- VAK List