СИНТЕЗ ТИАЗОЛОВ, СОДЕРЖАЩИХ АРИЛЕНАМИНОВУЮ/АЗА-ЕНАМИНОВУЮ БОКОВУЮ ГРУППУ. ВЛИЯНИЕ СИСТЕМЫ Π-СОПРЯЖЕНИЯ И ВОДОРОДНЫХ СВЯЗЕЙ НА ФОТОФИЗИЧЕСКИЕ СВОЙСТВА: статья в сборнике статей

Translated title of the contribution: SYNTHESIS OF THIAZOLES CONTAINING ARYL ENAMINE/AZA-ENAMINE SIDE CHAINS. EFFECT OF THE π-CONJUGATUION AND HYDROGEN BONDING ON PHOTOPHYSICAL PROPERTIES

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

An efficient synthesis of a new series of thiazoles containing aryl enamine side chains was developed, and the photophysical properties of the obtained compounds were compared with their structural analogues bearing the isoelectronic azaenamine group. Spectral characterization has demonstrated the difference in the absorption and fluorescence of the enamino- and aza-enaminothiazoles in solution and emergence of fluorescence enaminothiazoles in solid state. The availability, synthetic simplicity, stability, large Stokes shifts, and solvatochromic behaviour make the obtained thiazoles convenient for the further design and synthesis of new fluorophores.
Translated title of the contributionSYNTHESIS OF THIAZOLES CONTAINING ARYL ENAMINE/AZA-ENAMINE SIDE CHAINS. EFFECT OF THE π-CONJUGATUION AND HYDROGEN BONDING ON PHOTOPHYSICAL PROPERTIES
Original languageRussian
Title of host publicationАКТУАЛЬНЫЕ ПРОБЛЕМЫ РАЗВИТИЯ ЕСТЕСТВЕННЫХ НАУК
Subtitle of host publicationсборник статей
EditorsДарья Алексеевна Костина
Place of PublicationМосква
PublisherОбщество с ограниченной ответственностью "Эдитус"
Pages59-62
ISBN (Print)978-5-00058-763-8
Publication statusPublished - 2018

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