СОЧЕТАНИЕ РЕАКЦИЙ SNH/АЗА-ДИЛЬСА-АЛЬДЕРА КАК ЭФФЕКТИВНЫЙ СПОСОБ ПОЛУЧЕНИЯ 8-ГИДРОКСИ(МЕТОКСИ)ЗАМЕЩЕННЫХ 2-[6-(1-МЕТИЛИНДОЛ-3-ИЛ)ПИРИДИН-2-ИЛ]-ХИНОЛИНОВЫХ ЛИГАНДОВ/ФЛУОРОФОРОВ

Translated title of the contribution: COMBINATION OF THE SNH/AZA-DIELS-ALDER REACTIONS AS EFFECTIVE SYNTHETIC APPROACH TO 8-HYDROXY(METHOXY)-SUBSTITUTED 2-[6-(1-METHYLINDOL-3-YL)PYRIDIN-2-YL]QUINOLINE LIGANDS/FLUOROPHORES

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Abstract

8-Hydroxy(methoxy)-substituted 2-[6-(1-methylindol-3-yl)pyridin-2-yl]quinoline ligands were synthesized by means of combination of SNH reaction between 8-methoxy-substituted 2-(6-aryl-1,2,4-triazin-3-yl)quinolones and indole and aza-Diels-Alder reaction of the obtained 1,2,4-triazines with 2,5-norbornadiene. The demethylation of quinolone moiety of 1,2,4-triazine precursor during aza-Diels-Alder reaction in autoclave was demonstrated.
Translated title of the contribution COMBINATION OF THE SNH/AZA-DIELS-ALDER REACTIONS AS EFFECTIVE SYNTHETIC APPROACH TO 8-HYDROXY(METHOXY)-SUBSTITUTED 2-[6-(1-METHYLINDOL-3-YL)PYRIDIN-2-YL]QUINOLINE LIGANDS/FLUOROPHORES
Original languageRussian
Pages (from-to)688-693
Number of pages6
JournalЖурнал общей химии
Volume91
Issue number5
DOIs
Publication statusPublished - 2021

GRNTI

  • 31.21.00

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  • VAK List

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