ЭФФЕКТИВНЫЙ СИНТЕЗ ПИЛЛАР[5]АРЕНОВ И ПИЛЛАР[6]АРЕНОВ В КАЧЕСТВЕ НОВЫХ СИНТЕТИЧЕСКИХ РЕЦЕПТОРОВ АЦЕТИЛХОЛИНА

Translated title of the contribution: Efficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors

Григорий Васильевич Зырянов, Дмитрий Сергеевич Копчук, Владимир Леонидович Русинов, Олег Николаевич Чупахин, Алиса Анатольевна Майер, Олег Станиславович Ельцов, Игорь Сергеевич Ковалев, Альберт Фаридович Хасанов, Дмитрий Рудкевич

Research output: Contribution to journal › Article

Abstract

An efficient synthesis of pillar [5] - and pillar [6] arenes with alkyl substituents of various lengths from commercially available reagents (1,4-dialkoxybenzene and paraformaldehyde or 1,3,5-trioxane in the presence of Lewis acids) has been worked out. Cyclooligomerization products were isolated in high yields and with high oligoselectivity. In the presence of acetylcholine 1,4-bis(dodecyloxy)pillar[5]arene forms the inclusion complex in the ratio 1:1, which is observed by 1Н NMR method.
Translated title of the contributionEfficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors
Original languageRussian
Pages (from-to)131-135
Number of pages5
JournalБутлеровские сообщения
Volume34
Issue number5
Publication statusPublished - 2013

GRNTI

  • 31.00.00 CHEMISTRY

Level of Research Output

  • VAK List

Access to Document

Fingerprint Dive into the research topics of 'Efficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors'. Together they form a unique fingerprint.

Cite this