ЭФФЕКТИВНЫЙ СИНТЕЗ ПИЛЛАР[5]АРЕНОВ И ПИЛЛАР[6]АРЕНОВ В КАЧЕСТВЕ НОВЫХ СИНТЕТИЧЕСКИХ РЕЦЕПТОРОВ АЦЕТИЛХОЛИНА

Translated title of the contribution: Efficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors

Research output: Contribution to journalArticle

Abstract

An efficient synthesis of pillar [5] - and pillar [6] arenes with alkyl substituents of various lengths from commercially available reagents (1,4-dialkoxybenzene and paraformaldehyde or 1,3,5-trioxane in the presence of Lewis acids) has been worked out. Cyclooligomerization products were isolated in high yields and with high oligoselectivity. In the presence of acetylcholine 1,4-bis(dodecyloxy)pillar[5]arene forms the inclusion complex in the ratio 1:1, which is observed by 1Н NMR method.
Translated title of the contributionEfficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors
Original languageRussian
Pages (from-to)131-135
Number of pages5
JournalБутлеровские сообщения
Volume34
Issue number5
Publication statusPublished - 2013

GRNTI

  • 31.00.00 CHEMISTRY

Level of Research Output

  • VAK List

Fingerprint Dive into the research topics of 'Efficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors'. Together they form a unique fingerprint.

Cite this