Transition metal-free oxidative and deoxygenative C-H/C-Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

Research output: Contribution to journalArticleResearchpeer-review

1 Citation (Scopus)
Original languageEnglish
Pages (from-to)2618-2626
Number of pages9
JournalBeilstein Journal of Organic Chemistry
Volume14
DOIs
Publication statusPublished - 12 Oct 2018

Keywords

  • carboranes
  • C-H functionalization
  • C-H/C-Li cross-coupling
  • 2H-imidazole 1-oxide
  • nucleophilic substitution of hydrogen (S-N(H))
  • NUCLEOPHILIC AROMATIC-SUBSTITUTION
  • NEUTRON-CAPTURE THERAPY
  • ECONOMIC PASE SYNTHESIS
  • BIOLOGICAL EVALUATION
  • IRIDIUM(III) COMPLEXES
  • H FUNCTIONALIZATION
  • O-CARBORYNE
  • BORON
  • POLYMERIZATION
  • CYCLOADDITION

ASJC Scopus subject areas

  • Organic Chemistry

WoS ResearchAreas Categories

  • Chemistry, Organic

Cite this

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title = "Transition metal-free oxidative and deoxygenative C-H/C-Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes",
keywords = "carboranes, C-H functionalization, C-H/C-Li cross-coupling, 2H-imidazole 1-oxide, nucleophilic substitution of hydrogen (S-N(H)), NUCLEOPHILIC AROMATIC-SUBSTITUTION, NEUTRON-CAPTURE THERAPY, ECONOMIC PASE SYNTHESIS, BIOLOGICAL EVALUATION, IRIDIUM(III) COMPLEXES, H FUNCTIONALIZATION, O-CARBORYNE, BORON, POLYMERIZATION, CYCLOADDITION",
author = "Varaksin, {Mikhail V.} and Slepukhin, {Pavel A.} and Chupakhin, {Oleg N.} and Charushin, {Valery N.} and Smyshliaeva, {Lidia A.}",
year = "2018",
month = "10",
day = "12",
doi = "10.3762/bjoc.14.240",
language = "English",
volume = "14",
pages = "2618--2626",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

}

TY - JOUR

T1 - Transition metal-free oxidative and deoxygenative C-H/C-Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

AU - Varaksin, Mikhail V.

AU - Slepukhin, Pavel A.

AU - Chupakhin, Oleg N.

AU - Charushin, Valery N.

AU - Smyshliaeva, Lidia A.

PY - 2018/10/12

Y1 - 2018/10/12

KW - carboranes

KW - C-H functionalization

KW - C-H/C-Li cross-coupling

KW - 2H-imidazole 1-oxide

KW - nucleophilic substitution of hydrogen (S-N(H))

KW - NUCLEOPHILIC AROMATIC-SUBSTITUTION

KW - NEUTRON-CAPTURE THERAPY

KW - ECONOMIC PASE SYNTHESIS

KW - BIOLOGICAL EVALUATION

KW - IRIDIUM(III) COMPLEXES

KW - H FUNCTIONALIZATION

KW - O-CARBORYNE

KW - BORON

KW - POLYMERIZATION

KW - CYCLOADDITION

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DO - 10.3762/bjoc.14.240

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JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

ER -