АДИАБАТИЧЕСКАЯ СЖИМАЕМОСТЬ РАССЛАИВАЮЩЕЙСЯ РАСПЛАВЛЕННОЙ СОЛЕВОЙ СМЕСИ NАСL-АGI

Виктор Петрович Степанов, Н. К. Ткачев, Н.П. Кулик, К. Г. Пешкина

Resultado de la investigación: Articlerevisión exhaustiva

Resumen

The adiabatic compressibility, P, of the immiscible liquid mixture 0.5 NaCl + 0.5 AgI in the range of immiscibility was investigated both experimentally and through the use of a model of charged hard spheres with different diameters. Experimentally, the compressibility was studied using the sound velocity values, u, measured by the pulse method, and the density quantities, p, which were determined using the hydrostatic weight procedure based on the relationship P = 1/u[1] p. We show that the compressibility of the upper phase decreases but that of the lower phase increases when the temperature rises because of the superposition of the intensity of the thermal motion of the ions and the change in the composition of the phases. The difference, ДР, in the magnitudes of the compressibility for the equilibrium phases decreases with temperature elevation. The temperature dependence of the compressibility difference is described using the empirical equation ДР = (Tc - J)0-442, which is close to the mean-field theoretical description. The results of the model calculations sufficiently reproduce the experimentally observed temperature dependence of the compressibility of the coexisting phases. However, note that the theoretically predicted critical exponent (1/2) is different from that determined experimentally by 13%. The results are discussed in terms of the chemical bond nature of AgI.
Título traducido de la contribuciónAdiabatic compressibility of the immersible molten salt mixture NaCl-AgI
Idioma originalRussian
Páginas (desde-hasta)23-33
Número de páginas11
PublicaciónРасплавы
N.º6
EstadoPublished - 2015

GRNTI

  • 31.15.00

Level of Research Output

  • VAK List

Huella

Profundice en los temas de investigación de 'АДИАБАТИЧЕСКАЯ СЖИМАЕМОСТЬ РАССЛАИВАЮЩЕЙСЯ РАСПЛАВЛЕННОЙ СОЛЕВОЙ СМЕСИ NАСL-АGI'. En conjunto forman una huella única.

Citar esto