Resumen

An efficient synthesis of pillar [5] - and pillar [6] arenes with alkyl substituents of various lengths from commercially available reagents (1,4-dialkoxybenzene and paraformaldehyde or 1,3,5-trioxane in the presence of Lewis acids) has been worked out. Cyclooligomerization products were isolated in high yields and with high oligoselectivity. In the presence of acetylcholine 1,4-bis(dodecyloxy)pillar[5]arene forms the inclusion complex in the ratio 1:1, which is observed by 1Н NMR method.
Título traducido de la contribuciónEfficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors
Idioma originalRussian
Páginas (desde-hasta)131-135
Número de páginas5
PublicaciónБутлеровские сообщения
Volumen34
N.º5
EstadoPublished - 2013

GRNTI

  • 31.00.00 CHEMISTRY

Level of Research Output

  • VAK List

Huella Profundice en los temas de investigación de 'ЭФФЕКТИВНЫЙ СИНТЕЗ ПИЛЛАР[5]АРЕНОВ И ПИЛЛАР[6]АРЕНОВ В КАЧЕСТВЕ НОВЫХ СИНТЕТИЧЕСКИХ РЕЦЕПТОРОВ АЦЕТИЛХОЛИНА'. En conjunto forman una huella única.

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