Resumo

Using the gel synthesis approach of polymer-analogous transformations, N-sulfoethylation of polyethylenimine was carried out by treating the polymer with sodium vinyl sulfonate. The compositions and structures of the products were characterized by elemental analysis, FT-IR spectroscopy, and 1H NMR spectroscopy. At pH 3.0-4.5 sulfoethylated polyethylenimine can selectively extract AgI and CuII from an ammonia-acetate buffer solution in the presence of a series of transition and alkaline-earth metals. At pH > 6.5 the sorbent can be used for the group extraction of a number of transition metal ions. The structural feature of the obtained derivative eliminates the selectivity of sorption of AgI ions compared to CuII ions, which has previously been revealed for the sulfoethylated derivatives of chitosan and polyaminostyrene.
Título traduzido da contribuiçãoSulfoethylated polyethylenimine: synthesis in gel and sorption properties
Idioma originalRussian
Páginas (de-até)1252-1256
Número de páginas5
RevistaИзвестия Академии наук. Серия химическая
Número de emissão6
Estado da publicaçãoPublished - 2019

GRNTI

  • 31.00.00 CHEMISTRY

Level of Research Output

  • VAK List

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Mergulhe nos tópicos de investigação de “СУЛЬФОЭТИЛИРОВАННЫЙ ПОЛИЭТИЛЕНИМИН: СИНТЕЗ В ГЕЛЕ И СОРБЦИОННЫЕ СВОЙСТВА“. Em conjunto formam uma impressão digital única.

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