RELAY-RACE NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN IN ARENES AND HETEROARENES

O. N. Chupakhin

RELAY-RACE NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN IN ARENES AND HETEROARENES

Результат исследований: Вклад в журнал › Статья

Аннотация

The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called "relay-race" mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.

Язык оригинала	Русский
Страницы (с-по)	110-114
Число страниц	5
Журнал	Izvestiya sibirskogo otdeleniya akademii nauk sssr seriya khimicheskikh nauk
Номер выпуска	4
Состояние	Опубликовано - июл 1990

Ключевые слова

POTASSIUM-AMIDE
LIQUID-AMMONIA
DIDEHYDROHETARENES
DERIVATIVES

Предметные области WoS

Химия, Междисциплинарные труды

Ссылки

https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=A1990FF33200012

Цитировать

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abstract = "The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called {"}relay-race{"} mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.",

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AU - Chupakhin, O. N.

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N2 - The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called "relay-race" mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.

AB - The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called "relay-race" mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.

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KW - LIQUID-AMMONIA

KW - DIDEHYDROHETARENES

KW - DERIVATIVES

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M3 - Статья

SP - 110

EP - 114

JO - Известия Сибирского отделения Академии наук СССР. Серия химических наук

JF - Известия Сибирского отделения Академии наук СССР. Серия химических наук

SN - 0002-3426

IS - 4

ER -