RELAY-RACE NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN IN ARENES AND HETEROARENES

Результат исследований: Вклад в журналСтатьяНаучно-исследовательскаярецензирование

Аннотация

The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called "relay-race" mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.

Язык оригиналаРусский
Страницы (с-по)110-114
Число страниц5
ЖурналIzvestiya sibirskogo otdeleniya akademii nauk sssr seriya khimicheskikh nauk
Номер выпуска4
СостояниеОпубликовано - июл 1990

Ключевые слова

  • POTASSIUM-AMIDE
  • LIQUID-AMMONIA
  • DIDEHYDROHETARENES
  • DERIVATIVES

Предметные области WoS

  • Химия, Многопрофильные области

Цитировать

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abstract = "The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called {"}relay-race{"} mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.",
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RELAY-RACE NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN IN ARENES AND HETEROARENES. / Chupakhin, O. N.

В: Izvestiya sibirskogo otdeleniya akademii nauk sssr seriya khimicheskikh nauk, № 4, 07.1990, стр. 110-114.

Результат исследований: Вклад в журналСтатьяНаучно-исследовательскаярецензирование

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AB - The report reviews reactions of aromatic nucleophilic substitution of hydrogen, which are characterized by the so called "relay-race" mechanisms of aromatization of intermediate anionic sigma-complexes. This mechanism includes transfer of the reaction center from geminate hydrogene to other parts of intermediate sigma-complex, especially to atoms or groups of atoms which are capable to form stabilized anionic species.

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KW - LIQUID-AMMONIA

KW - DIDEHYDROHETARENES

KW - DERIVATIVES

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JO - ИЗВЕСТИЯ СИБИРСКОГО ОТДЕЛЕНИЯ АКАДЕМИИ НАУК СССР. СЕРИЯ ХИМИЧЕСКИХ НАУК

JF - ИЗВЕСТИЯ СИБИРСКОГО ОТДЕЛЕНИЯ АКАДЕМИИ НАУК СССР. СЕРИЯ ХИМИЧЕСКИХ НАУК

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