摘要

An efficient synthesis of pillar [5] - and pillar [6] arenes with alkyl substituents of various lengths from commercially available reagents (1,4-dialkoxybenzene and paraformaldehyde or 1,3,5-trioxane in the presence of Lewis acids) has been worked out. Cyclooligomerization products were isolated in high yields and with high oligoselectivity. In the presence of acetylcholine 1,4-bis(dodecyloxy)pillar[5]arene forms the inclusion complex in the ratio 1:1, which is observed by 1Н NMR method.
投稿的翻译标题Efficient synthesis of pillar[5]arenes and pillar[6]arenes as the new synthetic acetylcholine receptors
源语言Russian
页(从-至)131-135
页数5
期刊Бутлеровские сообщения
34
5
Published - 2013

GRNTI

  • 31.00.00 CHEMISTRY

Level of Research Output

  • VAK List

指纹 探究 'ЭФФЕКТИВНЫЙ СИНТЕЗ ПИЛЛАР[5]АРЕНОВ И ПИЛЛАР[6]АРЕНОВ В КАЧЕСТВЕ НОВЫХ СИНТЕТИЧЕСКИХ РЕЦЕПТОРОВ АЦЕТИЛХОЛИНА' 的科研主题。它们共同构成独一无二的指纹。

引用此